Press Release:

HP, UCLA Collaboration Receives Key Molecular Electronics Patent

Hewlett-Packard Company (NYSE:HWP) and UCLA today announced they have received a U.S. patent for technology that could make it possible to build very complex logic chips -- simply and inexpensively -- at the molecular scale.

The collaboration is pursuing molecular electronics as an entirely new technology that could augment silicon-based integrated circuits within the decade and eventually replace them. Most experts believe that silicon technology will reach its physical and economic limits by about 2012.

The patent(1), issued to Philip J. Kuekes and R. Stanley Williams ofHPLabs and James R. Heath of UCLA, builds on previous patents and scientific work by the company and university, working under a grant from the U.S. Defense Advanced Research Projects Agency, with matching funds fromHP.

Today's chip manufacturing process involves multiple, expensive precision steps to create the complex patterns of wires that define the computer circuit. TheHPand UCLA invention proposes the use of a simple grid of wires -- each wire just a few atoms wide -- connected by electronic switches a single molecule thick.

Previously,HPdemonstrated in the laboratory how some rare earth metals naturally form themselves into nanoscopic parallel wires when they react chemically with a silicon substrate. Two sets of facing parallel wires, oriented roughly perpendicular to each other, could then be made into a grid, like a map of Manhattan in New York City with streets running east-west and avenues north-south.

In a related experiment, researchers from the collaboration crossed wires the size of those used in today's computer chips and sandwiched them around a one-molecule thick layer of electrically switchable molecules called rotaxanes. Simple logic gates were then created electronically by downloading signals to molecules trapped between the crosswires.

"That work demonstrated for the first time that molecules could be used as electronic devices to perform computer logic," said Heath, UCLA chemistry professor and director of the California Nanosystems Institute.

TheHPand UCLA collaboration has also patented a memory chip based on molecular switches. This invention(2) was named one of the top five patents of 2000 by Technology Review, a journal of the Massachusetts Institute of Technology.

"All of this work demonstrates that, in the future, programming could replace today's complex, high-precision method of fabricating computer chips," said Kuekes, a senior scientist and computer architect atHPLabs. "Once a basic grid has been assembled, programming could be used to implement a very complex logic design by electronically setting the appropriate configuration switches in the molecular-scale structure."

But while simple logic circuits have been formed in previous experiments, until the most recent patent, a conceptual barrier remained to taking full advantage of the technology and creating practical, more complex chips.

"The problem is that on a single large grid all the electrical signals would interfere with each other," said Williams,HPFellow and director of quantum science research,HPLabs. "It would be like removing all the traffic signals from Manhattan and demanding a minimum speed of 30 mph -- the result would be total gridlock. Signal lights, or cut wires, regulate the flow of traffic and make it possible to carry passengers, or information, between any two points on the grid."

The solution proposed by the patented invention is to cut the wires into smaller lengths by turning some "intersections" into insulators.

"Essentially, you subdivide the city into smaller neighborhoods, with smaller local streets within each neighborhood and larger streets connecting the neighborhoods," Williams said.

The insulators are created by "cutter wires," which are chemically distinct from the others. A voltage difference between the cutter wire and the target wire creates the insulator.

Controlling these voltages and charges also has been the subject of a previous patent(3), issued to Williams and Kuekes last year, which provided a method to connect the molecular-scale devices to current technology, whose components are typically about 100 times larger. Generally speaking, this control involves a special demultiplexing technique using a chemical process to connect lithographically formed wires to the nanometer-scale wires.

About UCLA and the California NanoSystems Institute

UCLA ( is one of the world's premier universities, renowned for cutting-edge research and innovation, undergraduate and graduate education and community service. UCLA and UC Santa Barbara have joined to build the California NanoSystems Institute (, which will help to develop the informational, biomedical and manufacturing technologies -- the nanotechnologies -- that will be so influential in science and the economy in our new century.


Hewlett-Packard Company -- a leading global provider of computing and imaging solutions and services -- is focused on making technology and its benefits accessible to all.HPhad total revenue of $45.2 billion in its 2001 fiscal year. Information aboutHPand its products can be found on the World Wide Web at

(1) US 6,314,019 B1, "Molecular-Wire Crossbar Interconnect (MWCI) for Signal Routing and Communications."

(2) US 6,128,214, "Molecular Wire Crossbar Memory."

(3) US 6,256,767, "Demultiplexer for a Molecular Wire Crossbar."

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